Λογισμός Ket & bra
Braket notation, Συμβολισμός Dirac
 Ένας ιδιαίτερος Μαθηματικός Λογισμός (χρησιμοποιούμενος στην Κβαντική Φυσική).
Περιεχόμενα
Ετυμολογία[]
Η ονομασία "λογισμός" σχετίζεται ετυμολογικά με την λέξη "λόγος".
Εισαγωγή[]
In quantum mechanics, bra–ket notation is a standard notation for describing quantum states, composed of angle brackets and vertical bars.
It can also be used to denote abstract vectors and linear functionals in mathematics. In such terms, the scalar product, or action of a linear functional on a vector in a complex vector space, is denoted by
 ,
consisting of a left part,
called the bra, and a right part,
 ,
called the ket.
The notation was introduced in 1939 by Paul Dirac and is also known as the Dirac notation, though the notation has precursors in Grassmann's use of the notation
for his inner products nearly 100 years earlier. The relevant quantity is actually
and is interpreted according to the fundamental Born rule.
Braket notation is widespread in quantum mechanics.
Many phenomena that are explained using quantum mechanics are usually most clearly demonstrated with the help of the braket notation. Part of the appeal of the notation is the abstract representationindependence it encodes, together with its versatility in producing a specific representation (e.g. x, or p, or eigenfunction base) without much ado, or excessive reliance on the nature of the linear spaces involved.
The standard mathematical notation for the inner product, preferred as well by some physicists, expresses exactly the same thing as the braket notation,
where the far right gives the value of the linear functional (the bra) on its argument (the ket), and one can choose freely to interpret the left argument of braket as either a bra or a ket according to whether the far right or far left expression is the one thought of. It is only when a bra appears unpaired in an expression, such as,
that one should be aware that the bra technically is an element of the dual space of Hilbert space. It is in handling expressions containing these that the Dirac notation comes into its own. The notation does not introduce or imply any new physics.
Vector spaces[]
Background: Vector spaces[]
In physics, basis vectors allow any Euclidean vector to be represented geometrically using angles and lengths, in different directions, i.e. in terms of the spatial orientations.
It is simpler to see the notational equivalences between ordinary notation and braket notation; so, for now, consider a vector A starting at the origin and ending at an element of 3d Euclidean space; the vector then is specified by this endpoint, a triplet of elements in the field of real numbers, symbolically dubbed as A ∈ ℝ^{3}.
The vector A can be written using any set of basis vectors and corresponding coordinate system.
Informally basis vectors are like "building blocks of a vector": they are added together to compose a vector, and the coordinates are the numerical coefficients of basis vectors in each direction.
Two useful representations of a vector are simply
 a linear combination of basis vectors, and
 column matrices.
Using the familiar Cartesian basis, a vector A may be written as:
respectively,
 where:
 e_{x}, e_{y}, e_{z} denote the Cartesian basis vectors (all are orthogonal unit vectors) and A_{x}, A_{y}, A_{z} are the corresponding coordinates, in the x, y, z directions.
In a more general notation, for any basis in 3d space one writes
Generalizing further, consider a vector A in an Ndimensional vector space over the field of complex numbers ℂ, symbolically stated as A ∈ ℂ^{N}. The vector A is still conventionally represented by a linear combination of basis vectors or a column matrix:
though the coordinates are now all complexvalued.
Even more generally, A can be a vector in a complex Hilbert space. Some Hilbert spaces, like ℂ^{N}, have finite dimension, while others have infinite dimension. In an infinitedimensional space, the columnvector representation of A would be a list of infinitely many complex numbers.
Ket notation for vectors[]
Rather than boldtype, over arrows, underscores etc. conventionally used elsewhere, , Dirac's notation for a vector uses vertical bars and angular brackets: . When this notation is used, these vectors are called "ket", read as "ketA".^{[1]} This applies to all vectors, the resultant vector and the basis. The previous vectors are now written
or in a more easily generalized notation,
The last one may be written in short as
Note how any symbols, letters, numbers, or even words—whatever serves as a convenient label—can be used as the label inside a ket. In other words, the symbol "" has a specific and universal mathematical meaning, while just the A by itself does not.
Nevertheless, for convenience, there is usually some logical scheme behind the labels inside kets, such as the common practice of labeling energy eigenkets in quantum mechanics through a listing of their quantum numbers.
Further note that a ket and its representation by a coordinate vector are not the same mathematical object: a ket does not require specification of a basis, whereas the coordinate vector needs a basis in order to be well defined (the same holds for an operator and its representation by a matrix).^{[2]}
In this context, one should best use a symbol different than the equal sign, for example the symbol ≐, read as "is represented by".
Inner products and bras[]
An inner product is a generalization of the dot product.
The inner product of two vectors is a scalar. braket notation uses a specific notation for inner products:
For example, in threedimensional complex Euclidean space,
where denotes the complex conjugate of A_{i}.
A special case is the inner product of a vector with itself, which is the square of its norm (magnitude):
braket notation splits this inner product (also called a "bracket") into two pieces, the "bra" and the "ket":
where is called a bra, read as "braA", and is a ket as above.
The purpose of "splitting" the inner product into a bra and a ket is that both the bra and the ket are meaningful on their own, and can be used in other contexts besides within an inner product. There are two main ways to think about the meanings of separate bras and kets:
Bras and kets as row and column vectors[]
For a finitedimensional vector space, using a fixed orthonormal basis, the inner product can be written as a matrix multiplication of a row vector with a column vector:
Based on this, the bras and kets can be defined as:
and then it is understood that a bra next to a ket implies matrix multiplication.
The conjugate transpose (also called Hermitian conjugate) of a bra is the corresponding ket and vice versa:
because if one starts with the bra
then performs a complex conjugation, and then a matrix transpose, one ends up with the ket
Bras as linear transformation on kets[]
A more abstract definition, which is equivalent but more easily generalized to infinitedimensional spaces, is to say that bras are linear functionals on kets, i.e. linear transformations that input a ket and output a complex number. The bra linear functionals are defined to be consistent with the inner product.
In mathematics terminology, the vector space of bras is the dual space to the vector space of kets, and corresponding bras and kets are related by the Riesz representation theorem.
Nonnormalizable states and nonHilbert spaces[]
braket notation can be used even if the vector space is not a Hilbert space.
In quantum mechanics, it is common practice to write down kets which have infinite norm, i.e. nonnormalisable wavefunctions. Examples include states whose wavefunctions are Dirac delta functions or infinite plane waves. These do not, technically, belong to the Hilbert space itself. However, the definition of "Hilbert space" can be broadened to accommodate these states (see the Gelfand–Naimark–Segal construction or rigged Hilbert spaces). The braket notation continues to work in an analogous way in this broader context.
For a rigorous treatment of the Dirac inner product of nonnormalizable states, see the definition given by D. Carfì.
Banach spaces are a different generalization of Hilbert spaces. In a Banach space B, the vectors may be notated by kets and the continuous linear functionals by bras.
Over any vector space without topology, we may also notate the vectors by kets and the linear functionals by bras. In these more general contexts, the bracket does not have the meaning of an inner product, because the Riesz representation theorem does not apply.
Usage in quantum mechanics[]
The mathematical structure of quantum mechanics is based in large part on linear algebra:
 Wave functions and other quantum states can be represented as vectors in a complex Hilbert space. (The exact structure of this Hilbert space depends on the situation.) In braket notation, for example, an electron might be in the "state" ψ>. (Technically, the quantum states are rays of vectors in the Hilbert space, as cψ corresponds to the same state for any nonzero complex number c.)
 Quantum superpositions can be described as vector sums of the constituent states. For example, an electron in the state 1> + i 2> is in a quantum superposition of the states 1> and 2>.
 Measurements are associated with linear operators (called observables) on the Hilbert space of quantum states.
 Dynamics are also described by linear operators on the Hilbert space. For example, in the Schrödinger picture, there is a linear time evolution operator U with the property that if an electron is in state ψ> right now, at a later time it will be in the state Uψ>, the same U for every possible ψ>.
 Wave function normalization is scaling a wave function so that its norm is 1.
Since virtually every calculation in quantum mechanics involves vectors and linear operators, it can involve, and often does involve, braket notation. A few examples follow:
Spinless position–space wave function[]
The Hilbert space of a spin0 point particle is spanned by a "position basis" r>, where the label r extends over the set of all points in position space. Since there are an uncountably infinite number of vector components in the basis, this is an uncountably infinitedimensional Hilbert space.
The dimensions of the Hilbert space (usually infinite) and position space (usually 1, 2 or 3) are not to be conflated.
Starting from any ket Ψ> in this Hilbert space, we can define a complex scalar function of r, known as a wavefunction:
 .
On the left side, Ψ(r) is a function mapping any point in space to a complex number; on the right side,
 Ψ> = ∫ d^{3}r Ψ(r) r>
is a ket.
It is then customary to define linear operators acting on wavefunctions in terms of linear operators acting on kets, by
For instance, the momentum operator p has the following form,
One occasionally encounters a sloppy expression like
though this is something of a (common) abuse of notation. The differential operator must be understood to be an abstract operator, acting on kets, that has the effect of differentiating wavefunctions once the expression is projected into the position basis,
even though, in the momentum basis, the operator amounts to a mere multiplication operator (by iħp).
Overlap of states[]
In quantum mechanics the expression is typically interpreted as the probability amplitude for the state ψ to collapse into the state φ. Mathematically, this means the coefficient for the projection of ψ onto φ. It is also described as the projection of state ψ onto state φ.
Changing basis for a spin1/2 particle[]
A stationary spin½ particle has a twodimensional Hilbert space. One orthonormal basis is:
where is the state with a definite value of the spin operator S_{z} equal to +1/2 and is the state with a definite value of the spin operator S_{z} equal to −1/2.
Since these are a basis, any quantum state of the particle can be expressed as a linear combination (i.e., quantum superposition) of these two states:

 where a_{ψ}, b_{ψ} are complex numbers.
A different basis for the same Hilbert space is:
defined in terms of S_{x} rather than S_{z}.
Again, any state of the particle can be expressed as a linear combination of these two:
In vector form, you might write
depending on which basis you are using. In other words, the "coordinates" of a vector depend on the basis used.
There is a mathematical relationship between a_{ψ}, b_{ψ}, c_{ψ}, d_{ψ}; see change of basis.
Misleading uses[]
There are a few conventions and abuses of notation that are generally accepted by the physics community, but which might confuse the noninitiated.
It is common to use the same symbol for labels and constants in the same equation. For example, α̂ Πρότυπο:Ket = αΠρότυπο:Ket, where the symbol α is used simultaneously as the name of the operator α̂, its eigenvector Πρότυπο:Ket and the associated eigenvalue α.
Something similar occurs in component notation of vectors. While Ψ (uppercase) is traditionally associated with wavefunctions, ψ (lowercase) may be used to denote a label, a wave function or complex constant in the same context, usually differentiated only by a subscript.
The main abuses are including operations inside the vector labels. This is usually done for a fast notation of scaling vectors. E.g. if the vector Πρότυπο:Ket is scaled by Πρότυπο:Sqrt, it might be denoted by Πρότυπο:Ket, which makes no sense since α is a label, not a function or a number, so you can't perform operations on it.
This is especially common when denoting vectors as tensor products, where part of the labels are moved outside the designed slot, e.g. Πρότυπο:Ket = Πρότυπο:Ket ⊗ Πρότυπο:Ket. Here part of the labeling that should state that all three vectors are different was moved outside the kets, as subscripts 1 and 2. And a further abuse occurs, since α is meant to refer to the norm of the first vector—which is a label denoting a value.
Linear operators[]
Πρότυπο:See also
Linear operators acting on kets[]
A linear operator is a map that inputs a ket and outputs a ket. (In order to be called "linear", it is required to have certain properties.) In other words, if A is a linear operator and Πρότυπο:Ket is a ket, then AΠρότυπο:Ket is another ket.
In an Ndimensional Hilbert space, Πρότυπο:Ket can be written as an N×1 column vector, and then A is an N×N matrix with complex entries. The ket AΠρότυπο:Ket can be computed by normal matrix multiplication.
Linear operators are ubiquitous in the theory of quantum mechanics. For example, observable physical quantities are represented by selfadjoint operators, such as energy or momentum, whereas transformative processes are represented by unitary linear operators such as rotation or the progression of time.
Linear operators acting on bras[]
Operators can also be viewed as acting on bras from the right hand side. Specifically, if A is a linear operator and Πρότυπο:Bra is a bra, then Πρότυπο:BraA is another bra defined by the rule
(in other words, a function composition). This expression is commonly written as (cf. energy inner product)
 .
In an Ndimensional Hilbert space, Πρότυπο:Bra can be written as a 1×N row vector, and A (as in the previous section) is an N×N matrix. Then the bra Πρότυπο:BraA can be computed by normal matrix multiplication.
If the same state vector appears on both bra and ket side,
then this expression gives the expectation value, or mean or average value, of the observable represented by operator A for the physical system in the state Πρότυπο:Ket.
Outer products[]
A convenient way to define linear operators on Hilbert space H is given by the outer product: if Πρότυπο:Bra is a bra and Πρότυπο:Ket is a ket, the outer product
denotes the rankone operator with the rule
 .
For a finitedimensional vector space, the outer product can be understood as simple matrix multiplication:
The outer product is an N×N matrix, as expected for a linear operator.
One of the uses of the outer product is to construct projection operators. Given a ket Πρότυπο:Ket of norm 1, the orthogonal projection onto the subspace spanned by Πρότυπο:Ket is
Hermitian conjugate operator[]
Πρότυπο:Main Just as kets and bras can be transformed into each other (making Πρότυπο:Ket into Πρότυπο:Bra), the element from the dual space corresponding to AΠρότυπο:Ket is Πρότυπο:BraA^{†}, where A^{†} denotes the Hermitian conjugate (or adjoint) of the operator A. In other words,
 if and only if .
If A is expressed as an N×N matrix, then A^{†} is its conjugate transpose.
Selfadjoint operators, where A = A^{†}, play an important role in quantum mechanics; for example, an observable is always described by a selfadjoint operator. If A
is a selfadjoint operator, then Πρότυπο:BraAΠρότυπο:Ket is always a real number (not complex). This implies that expectation values of observables are real.
Properties[]
braket notation was designed to facilitate the formal manipulation of linearalgebraic expressions. Some of the properties that allow this manipulation are listed herein. In what follows, c_{1} and c_{2} denote arbitrary complex numbers, c^{∗} denotes the complex conjugate of c, A and B denote arbitrary linear operators, and these properties are to hold for any choice of bras and kets.
Γραμμικότητα[]
 Since bras are linear functionals,
 By the definition of addition and scalar multiplication of linear functionals in the dual space,^{[3]}
Associativity[]
Given any expression involving complex numbers, bras, kets, inner products, outer products, and/or linear operators (but not addition), written in braket notation, the parenthetical groupings do not matter (i.e., the associative property holds). For example:
and so forth. The expressions on the right (with no parentheses whatsoever) are allowed to be written unambiguously because of the equalities on the left. Note that the associative property does not hold for expressions that include nonlinear operators, such as the antilinear time reversal operator in physics.
Hermitian conjugation[]
braket notation makes it particularly easy to compute the Hermitian conjugate (also called dagger, and denoted †) of expressions. The formal rules are:
 The Hermitian conjugate of a bra is the corresponding ket, and vice versa.
 The Hermitian conjugate of a complex number is its complex conjugate.
 The Hermitian conjugate of the Hermitian conjugate of anything (linear operators, bras, kets, numbers) is itself—i.e.,
 (x^{†})^{†} = x.
 Given any combination of complex numbers, bras, kets, inner products, outer products, and/or linear operators, written in braket notation, its Hermitian conjugate can be computed by reversing the order of the components, and taking the Hermitian conjugate of each.
These rules are sufficient to formally write the Hermitian conjugate of any such expression; some examples are as follows:
 Kets:
 Inner products:
 Matrix elements:
 Outer products:
Composite bras and kets[]
Two Hilbert spaces V and W may form a third space V ⊗ W by a tensor product. In quantum mechanics, this is used for describing composite systems. If a system is composed of two subsystems described in V and W respectively, then the Hilbert space of the entire system is the tensor product of the two spaces. (The exception to this is if the subsystems are actually identical particles. In that case, the situation is a little more complicated.)
If Πρότυπο:Ket is a ket in V and Πρότυπο:Ket is a ket in W, the direct product of the two kets is a ket in V ⊗ W. This is written in various notations:
See quantum entanglement and the EPR paradox for applications of this product.
The unit operator[]
Consider a complete orthonormal system (basis), , for a Hilbert space H, with respect to the norm from an inner product . From basic functional analysis we know that any ket Πρότυπο:Ket can also be written as
with the inner product on the Hilbert space.
From the commutativity of kets with (complex) scalars now follows that
must be the identity operator, which sends each vector to itself. This can be inserted in any expression without affecting its value, for example
 ,
where, in the last identity, the Einstein summation convention has been used.
In quantum mechanics, it often occurs that little or no information about the inner product of two arbitrary (state) kets is present, while it is still possible to say something about the expansion coefficients and of those vectors with respect to a specific (orthonormalized) basis. In this case, it is particularly useful to insert the unit operator into the bracket one time or more.
For more information, see Resolution of the identity, 1 = ∫ dx Πρότυπο:KetΠρότυπο:Bra = ∫ dp Πρότυπο:KetΠρότυπο:Bra, where Πρότυπο:Ket = ∫ dx e^{ixp/ħ}Πρότυπο:Ket/√Πρότυπο:Overline; since Πρότυπο:Braket = δ(x − x′), plane waves follow, Πρότυπο:Braket = exp(ixp/ħ)/√Πρότυπο:Overline.
Notation used by mathematicians[]
The object physicists are considering when using the "braket" notation is a Hilbert space (a complete inner product space).
Let be a Hilbert space and is a vector in . What physicists would denote as Πρότυπο:Ket is the vector itself. That is
 .
Let be the dual space of . This is the space of linear functionals on . The isomorphism is defined by where for all we have
 ,
where and are just different notations for expressing an inner product between two elements in a Hilbert space (or for the first three, in any inner product space). Notational confusion arises when identifying and with and respectively. This is because of literal symbolic substitutions. Let and let . This gives
One ignores the parentheses and removes the double bars. Some properties of this notation are convenient since we are dealing with linear operators and composition acts like a ring multiplication.
Moreover, mathematicians usually write the dual entity not at the first place, as the physicists do, but at the second one, and they don't use the *symbol, but an overline (which the physicists reserve for averages and Dirac conjugation) to denote conjugatecomplex numbers, i.e. for scalar products mathematicians usually write
whereas physicists would write for the same quantity
Υποσημειώσεις[]
 ↑ Quantum Mechanics Demystified, McMahon, McGrawHill, 2006
 ↑ Modern Quantum Mechanics, Sakurai, AddisonWesley, 1994
 ↑ Lecture notes by Robert Littlejohn, eqns 12 and 13
Εσωτερική Αρθρογραφία[]
 Κβαντική Κατάσταση
 ιδιοκατάσταση
 ιδιοδιάνυσμα
 Angular momentum diagrams
 Nslit interferometric equation
 Quantum state
 Inner product
Βιβλιογραφία[]
Ιστογραφία[]
 Ομώνυμο άρθρο στην Βικιπαίδεια
 Ομώνυμο άρθρο στην Livepedia
 Richard Fitzpatrick, "Quantum Mechanics: A graduate level course", The University of Texas at Austin. Includes:
 1. Ket space
 2. Bra space
 3. Operators
 4. The outer product
 5. Eigenvalues and eigenvectors
 Robert Littlejohn, Lecture notes on "The Mathematical Formalism of Quantum mechanics", including braket notation. Unviversity of California, Berkeley.
 MathPages
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